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Beilstein J. Org. Chem. 2012, 8, 1536–1542, doi:10.3762/bjoc.8.174
Graphical Abstract
Scheme 1: (a) Cobalt-catalyzed C2-alkenylation of N-pyrimidylindole, (b) ortho-alkylation of aryl imine, and ...
Scheme 2: Addition of N-pyrimidylindoles to vinylsilanes.
Scheme 3: Addition of N-pyrimidylindole to norbornene (a) and 1-octene (b).
Scheme 4: Gram-scale reaction and deprotection of N-pyrimidyl group.